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TECHNICAL PAPER


           It is noted that the most critical diameters of the references   micromorphology are generated in pastes after
           including P00 and PLS00 have few decrease at 365 days      rehydration reaction.
           compared with the critical diameters at 90 days in terms of
           Figure 6 - 7 though the rehydration degree and compressive   5.  ACKNOWLEDGMENTS
           strength of them have marked increase after 90 days. On the   This study was funded by the key project of Natural Science
           one hand, it may be because that the late age rehydration   Foundation of Anhui Polytechnic University (Xjky2022165), the
           degree of paste is obviously lower than early age hydration   Start Fund of Talent Introduction of Anhui Polytechnic University
           degree after all  [18] . In addition, the effect of cement hydration on   (2021YQQ062) and the Natural Science Research Project of
           the pore size refinement of paste is evidently inferior to that of   Universities in Anhui Province (KJ2021A0504).
           MK reaction  [35] . The outstanding increased compressive strength
           of the references at late ages may be attributed to apparently   Conflicts of Interest : The authors declare no conflict of interest.
           enhanced interfacial transfer zone (ITZ) of mortars by rehydration
           reaction  [36] .                                       REFERENCES

           3.5  Microstructures                                   [1]   Yu, R., Spiesz, P., and Brouwers, H. J. H. (2014). “Mix design
                                                                      and properties assessment of ultra-high performance fiber
           Figure 9 presents the micromorphology of long term water cued   reinforced concrete (UHPFRC)”, Cement and Concrete
           UHPC pastes at 365 days. It is indicated that MK blended pastes   Research, Vol. 56, No. 2, pp. 29-39.
           are covered with homogeneous gels due to MK reaction. While   [2]   Raheem, A. H. A., Mahdy, M., and Mashaly, A. A. (2019).
           dense microstructures also can be obtained in the references on   “Mechanical and fracture mechanics properties of ultra-
           account of significant rehydration degree from 90 to 365 days.   high-performance concrete”, Construction and Building
           Especially for that of LS cement paste (PLS00), compacted and   Materials, Vol. 213, No. 7, pp. 561-566.
           homogeneous gels cover the surfaces of matrix since increased   [3]   Yang, S. L., Millard, S. G., Soutsos, M. N., Barnett, S. J., and
           Al/Si ratio in gels can bring about densification of microstructure
                                                                      Le, T. T. (2009). “Influence of aggregate and curing regime
           of paste  [37] . While the XRD patterns in section 3.3 demonstrate   on the mechanical properties of ultra-high performance
           that a few LS participated in hydration reaction generating Mc,   fibre reinforced concrete (UHPFRC)”, Construction and
           which can improve Al/Si ratio of hydration products in PLS00   Building Materials, Vol. 23, No. 6, pp. 2291-2298.
           paste. Moreover, LS as the nucleation of hydration products   [4]   Wang, W., Liu, J., Agostini, A., Davy, C. A., Skoczylas.
           also can promote generating a superior matrix  [38] . In a word, the   F., and Corvez, D. (2014). “Durability of an ultra high
           homogeneous and compacted microstructures of pastes can be   performance fiber reinforced concrete (UHPFRC) under
           related to the ultra high mechanical property of mortars.  progressive aging”, Cement and Concrete Research,
                                                                      Vol. 55, No. 1, pp. 1-13.
           4. CONCLUSIONS                                         [5]   Tuan, N. V., Ye, G., Breugel, K. V., and Copuroglu, O. (2011).
           The mechanical property and rehydration of water cured UHPC   “Hydration and microstructure of ultra high performance
           pastes blended with MK from 90 to 365 days were studied in this   concrete incorporating rice husk ash”, Cement and
                                                                      Concrete Research, Vol. 41, No. 11, pp. 1104-1111.
           study. The follow conclusions have been drawn.
                                                                  [6]   Huang, H., Gao, X., Wang, H., and Ye, H. (2017). “Influence
           1.   MK pozzolanic reaction markedly alleviates the strength
               development tendency of UHPC mortars with long term    of rice husk ash on strength and permeability of ultra-
                                                                      high performance concrete”, Construction and Building
               water curing in one year. Additionally, MK contained   Materials, Vol, 149, No. 9, pp. 621-628.
               mortars behave an excellent water resistance.
                                                                  [7]   Vigneshwari, M., Arunachalam, K., and Angayarkanni, A.
           2.   From 90 to 150 days, the rehydration degree of UHPC   (2018). “Replacement of silica fume with thermally treated
               pastes increased promptly. While after 150 days, the
                                                                      rice husk ash in reactive powder concrete”, Journal of
               rehydration rate of pastes obviously decreased.        Cleaner Production, Vol. 188, No. 7, pp. 264-277.
           3.   Cement hydration and MK reaction commonly constituted
                                                                  [8]   Tafraoui, A., Escadeillas, G., Lebaili, S., and Vidal, T. (2009).
               its rehydration reaction of pastes blended with MK. While   “Metakaolin in the formulation of UHPC”, Construction
               LS barely participated in the rehydration reaction including   and Building Materials, Vol. 23, No. 2, pp. 669-674.
               synergistic effect with MK.
                                                                  [9]   Tafraoui, A., Escadeillas, G., and Vidal, T. (2016). “Durability
           4.   Late age rehydration can generally refine the pores   of the ultra high performances concrete containing
               under 10 μm of pastes but also promote generating      metakaolin”, Construction and Building Materials, Vol. 112,
               large pores(>100 μm). Homogeneous and compacted        No. 6, pp. 980-987.


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